水热–热解生物炭影响硫铝酸盐砂浆力学性能与干湿耐久性机理研究
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国家自然科学基金项目(52300163)和山东省自然科学基金项目(ZR2024QE099)


Effects and Mechanism of Hydrothermal – Pyrolysis Biochar on Mechanical Properties and Dry – Wet Durability of Sulphoaluminate Mortar
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    摘要:

    为推动制药污泥、果木枝条等农林与工业生物质固废资源化高值利用,同时提升硫铝酸盐水泥(SAC)在滨海农业、滩涂养殖、沿海农田水利工程等硫酸盐干湿循环环境下的服役性能,本研究以制药污泥与果木枝条为原料,采用共水热炭化及耦合热解工艺制备水热热解生物炭(HPB),将其作为绿色改性组分掺入SAC砂浆,系统研究HPB掺量(1%、3%、5% )对砂浆力学性能、水化反应特性的影响,确定最优掺量并开展150次硫酸盐干湿循环实验,结合宏观性能测试与XRD、TG、SEM微观表征,揭示HPB对SAC砂浆的改性机制。掺量分析结果表明:砂浆抗压强度随HPB掺量的增加呈现先升高后降低的趋势;1% HPB掺量条件下抗压强度最高,其28d抗压强度达48MPa,较不掺HPB的对照组增加9.1% ;这主要是由于在SAC中添加1% HPB可延缓SAC砂浆中早期钙矾石的生成、促进后期水化反应持续进行,同时能够调控碳酸钙形成高稳定性方解石,并优化砂浆微观结构,从而使HPB SAC 1砂浆的后期强度最高。干湿循环分析结果表明:经150次干湿循环后,HPB-SAC 1砂浆的质量损失最低,仅为1.09% ,显著低于对照组的2.35% ,HPB-SAC 1砂浆表观仅轻微砂化,无剥落与骨料裸露,且力学性能下降周期延后约30次干湿循环。HPB能够通过抑制钙矾石过度生长、优化孔隙结构、降低硫酸根离子渗透,显著提升砂浆耐硫酸盐侵蚀能力。本研究实现了多源农林生物质固废制备功能改性剂调控水泥基材料特性的资源化利用新技术,为污泥、果木等生物质固废协同处置与滨海农业、滩涂养殖、沿海农田水利工程领域的胶凝材料绿色低碳改性提供科学依据与技术支撑。

    Abstract:

    Aiming to realize high-value utilization of biomass solid wastes such as pharmaceutical sludge and fruit branches, and improve the service performance of sulphoaluminate cement (SAC) in sulfate dry-wet cycling environment of coastal agriculture, tidal flats aquaculture, and coastal farmland water conservancy projects, hydrothermal-pyrolysis biochar ( HPB ) was prepared by co-hydrothermal carbonization coupled with pyrolysis. The effects of HPB content (1% , 3% , 5% ) on mechanical properties and hydration characteristics of SAC mortar were investigated, and 150 sulfate dry-wet cycles were conducted. Results showed that the compressive strength was firstly increased and then decreased with the increase of HPB content. The 28-day compressive strength reached 48 MPa at 1% HPB, 9.1% higher than that of the control. HPB retarded early ettringite formation, promoted late hydration, and optimized microstructure. After 150 cycles, the mass loss of 1% HPB mortar was only 1.09% , much lower than 2.35% of the control, and the performance degradation was delayed by about 30 cycles. HPB significantly enhanced sulfate resistance by inhibiting excessive ettringite growth, optimizing pore structure and reducing sulfate ion penetration. The research result can provide a scientific basis for biomass waste recycling and green modification of SAC mortar in coastal agriculture, tidal flats aquaculture, and coastal farmland water conservancy projects.

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张新雁,曹明皓,樊昊天,秦庆雨,胡芝娟,张祥坤,王文龙.水热–热解生物炭影响硫铝酸盐砂浆力学性能与干湿耐久性机理研究[J].农业机械学报,2026,57(21):139-150. Zhang Xinyan, Cao Minghao, Fan Haotian, Qin Qingyu, Hu Zhijuan, Zhang Xiangkun, Wang Wenlong. Effects and Mechanism of Hydrothermal – Pyrolysis Biochar on Mechanical Properties and Dry – Wet Durability of Sulphoaluminate Mortar[J]. Transactions of the Chinese Society for Agricultural Machinery,2026,57(21):139-150.

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  • 收稿日期:2026-07-19
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  • 在线发布日期: 2026-11-01
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