DRP温室透光覆盖材料性能表征研究
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“十二五”国家科技支撑计划项目(2014BAD08B020107)和校企合作科技攻关项目(GZXCZH201811002)


Performance Characterization of DRP Greenhouse Transparent Covering Material
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    摘要:

    以聚酯(PET)有光切片和含有机助剂的母料为主要原料,经过结晶干燥、熔融挤出铸片、纵横向拉伸等工艺,研发了具有高保温、高透光、高强度、耐老化的可降解并循环再生聚酯(Degradable recyclable polyester,DRP)农用薄膜,简称DRP薄膜。使用分光光度计、万能试验机和热重分析仪等仪器,采用对比分析法对该DRP薄膜的透射性、保温性、抗拉性能、抗撕裂性能、热稳定性以及耐老化性能进行了表征研究。结果显示,DRP薄膜在光合有效辐射波段透过率为90.73%;在中波紫外、中红外波段透过率分别为0.74%、14.56%,表明DRP薄膜有很强的阻隔中波紫外线能力以及优异的夜间保温能力。将覆盖于温室上自然老化约1 年的DRP薄膜与初始DRP薄膜的光学性能进行对比,结果表明,自然老化的DRP薄膜在光合有效辐射波段透过率降低3个百分点,5~25μm波段红外阻隔能力降低4.34个百分点,说明自然老化的DRP薄膜仍然具有较好的透光率和很强的红外阻隔能力。DRP薄膜纵向拉伸强度可达103.21MPa,可以满足正常使用要求。DRP薄膜纵向裤形撕裂强度为244.17kN/m,是PET膜的19.49倍。在升温到600℃的过程中,DRP薄膜发生了3次较为明显的失重现象,首次失重温度为250℃±5℃,可见其热稳定性较好。研究表明,DRP温室透光覆盖材料在透光、保温、力学性能和耐老化方面都具有突出的优势。

    Abstract:

    PET slices and masterbatch with organic synthetic additives were the main raw materials. Through crystallization drying, melt extrusion casting and longitudinal and transverse stretching, a degradable and recycled polyester agricultural film (DRP film) with high thermal insulation, high transparency, high strength and aging resistance was developed. The radiation transmittance, heat preservation ability, tensile properties, tear resistance, thermal stability and aging resistance of the DRP film were characterized by means of comparative analysis using spectrophotometer, universal testing machine and thermogravimetric analyzer. The results showed that the transmittance of DRP films in photosynthetic effective radiation wave range was 90.73%. The transmittance of ultraviolet radiation B and midinfrared was 0.74% and 14.56%, respectively, which showed that DRP film had a good ability to resist the ultraviolet radiation B and the heat preservation at night. In addition, by comparing the radiation transmittance properties of DRP films aged naturally for about one year over the greenhouse with that of initial DRP films, it was found that DRP films aged naturally declined only 3 percentage points in photosynthetic effective radiation wave range, and it still had good light transmittance. The radiation transmittance of DRP film was decreased only by 4.34 percentage points in 5000~25000 nm after aging, and it still had good heat preservation ability as the film of greenhouse at night. The longitudinal tensile strength of DRP film was 103.21MPa, which could meet the requirements of normal use. The longitudinal trouser tear strength of DRP film was 244.17kN/m, which was 19.49 times of that of PET film. DRP film had three obvious weightlessness phenomena during the temperature rise to 600℃ in thermogravimetric test. The first weightlessness temperature of DRP film was (250±5)℃, and it had better thermal stability. In conclusion, the DRP greenhouse transparent cover material had outstanding advantages in light transmission, heat preservation, mechanical properties and aging resistance.

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王宇欣,李丹春,黄斌,谢鑫,冯荣辉. DRP温室透光覆盖材料性能表征研究[J].农业机械学报,2020,51(4):320-327. WANG Yuxin, LI Danchun, HUANG Bin, XIE Xin, FENG Ronghui. Performance Characterization of DRP Greenhouse Transparent Covering Material[J]. Transactions of the Chinese Society for Agricultural Machinery,2020,51(4):320-327.

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  • 收稿日期:2019-11-28
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  • 在线发布日期: 2020-04-10
  • 出版日期: 2020-04-10