基于ISE的湿土硝态氮检测方法研究
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国家自然科学基金项目(61134011)


ISE-based Sensor Fusion Method for Wet Soil Nitrate-nitrogen Detection
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    摘要:

    分析了含水率对离子选择电极(ISE)湿土硝态氮直测的影响,建立了一种融合土壤含水率的ISE湿土直测方〖JP2〗法。结果表明:未修正含水率影响的ISE湿土直测结果与光学检测方法结果间的绝对偏差范围为3.79~44.81mg/L,〖JP〗均方根误差大于17.00mg/L,无法满足应用需求;湿土质量含水率、浸提液添加量及干土折算量间存在线性函数关系,融合湿土质量含水率的ISE湿土硝态氮直测结果与光学检测方法结果之间具有较好的一致性,与光学检测结果回归方程的调整决定系数为0.97,绝对偏差范围为0.17~17.95mg/L,均方根误差小于7.05mg/L,检测精度和稳定性与实验室ISE干土测定性能相近,比未修正含水率影响前有明显提高。

    Abstract:

    The nitratenitrogen (NO-3N) of wet soil samples was detected through sensor fusion method. The prediction model of NO-3N was established by ionselective electrode (ISE) and soil moisture sensor. The interference of water content on fast detection of wet soil was analyzed. The statistical linear transformation between soil mass water content and volumetric water content was determined through calibration experiments. The algebra relationship among soil water content, volume of soil extractant and mass of dry material was derived. Compared with the standard spectrometric detection, the poor prediction accuracy of root mean square error (RMSE) of more than 17.00mg/L was obtained in bare ISEbased NO-3N detections. Meanwhile, the average absolute error (AE) was 3.79~44.81mg/L, which indicated a nonnegligible predicted deviation from real soil NO-3N condition. Through the sensor fusion approach, the NO-3N prediction results indicated significantly good consistency with standard spectrometric detection results. The adjusted determination coefficient (R2) of regression equation was 0.97, RMSE was less than 7.05mg/L, and AE was 0.17~17.95mg/L. The sensor fusion method obviously improved the detection accuracy of nitratenitrogen detection compared with the bare ISE detection. Meanwhile, it demonstrated the advantage of higher efficiency than that of conventional laboratory soil detections which required soil pretreatment. The method and experimental results could provide references for ISE applications to online soil macronutrient fast detections.

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李雁华,张淼,潘林沛,郑杰.基于ISE的湿土硝态氮检测方法研究[J].农业机械学报,2016,47(s1):285-290.

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  • 收稿日期:2016-07-20
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  • 在线发布日期: 2016-10-15
  • 出版日期: 2016-10-15