超声波降解苹果汁中展青霉素动力学研究
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陕西省科技统筹创新工程计划资助项目(2015KTCL02-02)和“十二五”国家科技支撑计划资助项目(2012BAD31B01)


Kinetics Study of Ultrasonic Degradation of Patulin in Apple Juice
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    摘要:

    为了掌握超声波降解苹果汁中展青霉素的动力学特性,在前期超声波降解苹果汁中展青霉素的研究基础上,利用拟一级反应动力学方程对超声波影响因素中超声波功率、频率及温度降解苹果汁中展青霉素的试验数据进行拟合,确定相关参数,进一步建立各影响因素降解速率常数与相关影响因子之间的关系方程。结果表明:超声波功率对苹果汁中展青霉素的降解符合拟一级反应方程,超声波功率为490W时,降解率最大;功率降解速率常数kP与超声波功率的方程为kP=6×10-5P-0.0117。超声波频率对展青霉素的降解符合拟一级反应方程,超声波频率为45kHz时,降解率最大;频率降解速率常数kf与超声波频率f的关系方程为kf=-8×10-4f2+0.1119f-2.5126。〖JP〗温度对苹果汁中展青霉素的降解符合拟一级反应方程,温度为30℃时,降解率最大;温度降解速率常数kT与温度T的关系方程为kT=-1×10-4T2+0.0061T-0.0769。

    Abstract:

    China is the biggest apple juice concentrate producer in the world, while some security problems, especially patulin still occur in apple juice concentrate industry. These problems are obstacle to produce high quality apple juice concentrate in China. In order to reduce the content of patulin and improve the safety of apple juice, the kinetics of ultrasonic degradation of patulin in apple juice was studied. The pseudofirst order kinetics models were established to investigate the effect of ultrasonic power, frequency and temperature on the degradation of patulin. The results showed that the ultrasonic power was coincided with the pseudofirst order kinetics models in patulin degradation process. The biggest degradation rate was obtained at a power of 490W. The power degradation constant kP value increased with the enhancing power. The power degradation constant kP and the ultrasonic power P was kP=6×10-5P-0.0117. The ultrasonic frequencies were consitent with the pseudo-first order kinetics models in patulin degradation process. The results indicated that 45kHz was the optimal frequency. The frequencies degradation constant kf and the ultrasonic frequencies f was kf=-8×10-4f2+01119f-2.5126. The temperature was coincided with the pseudofirst order kinetics models in patulin degradation process. The results suggested that 30℃ was the optimal temperature. The temperature degradation constant kT and the temperature T was kT=-1×10-4T2+0.0061T-0.0769. The study of patulin degradation kinetics will resolve the pollution problem of patulin and provide the theoretical basis for industry controlling of patulin in the producing of cloudy apple juice and apple jam.

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高振鹏,刘 瑞,张德举,袁亚宏,岳田利.超声波降解苹果汁中展青霉素动力学研究[J].农业机械学报,2015,46(11):230-235.

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  • 收稿日期:2015-07-09
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  • 在线发布日期: 2015-11-10
  • 出版日期: 2015-11-10