超微粉碎玉米秸秆微观结构与秸秆-淀粉共混膜蠕变特性
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教育部高等学校博士学科点新教师基金项目(20130008120021)和国家自然科学基金项目(31301593)


Microstructure of Ball Milling Cornstalk and Creep Behavior of Corn Starch-based Films
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    摘要:

    为改善淀粉膜的性能,提高玉米秸秆的利用价值,研究了超微粉碎时间对玉米秸秆微观结构的影响,并选取超微粉碎1h的玉米秸秆与玉米淀粉共混制备秸秆-淀粉共混膜,研究了超微粉碎秸秆的添加量对淀粉基膜蠕变特性的影响,并进行了模型拟合。超微粉碎试验结果表明,超微粉碎1h的玉米秸秆维管束结构破坏较为完全,与对照样相比,平均粒径从85.33μm变为9.46μm,结晶度从39.46%变为19.29%。延长超微粉碎时间,秸秆粉体间团聚现象逐渐加剧,最终形成大颗粒团聚体。秸秆-淀粉共混膜蠕变特性测试结果表明,超微粉碎玉米秸秆的添加能显著改善共混膜的粘弹特性和蠕变特性。当添加量不大于15%时,超微粉碎秸秆-淀粉膜的蠕变形变、蠕变柔量和不可恢复形变都会随着添加量的增加而减小。当秸秆添加量达到淀粉用量的20%时,淀粉膜的蠕变特性有减弱的趋势。模型拟合结果表明,Burgers模型能很好地拟合秸秆-淀粉膜的蠕变-恢复测试结果,决定系数均达到0.98以上。

    Abstract:

    To improve the property of starch film and the additional value of cornstalk, this paper studied the effects of ultrafine grinding time on the composition structure of cornstalk. And 1h ultrafine grinding cornstalk was selected to prepare films with starch. Then the creep and creep-recovery behavior of starch-based films were investigated, to which different content of ball milling cornstalk was added. The results showed that after 1h ball-milling, the fiber bundle and the cell wall of cornstalk can be damaged relatively completely. Comparing with control sample, the particle size and crystallinity were decreased significantly, from 85.33μm to 9.46μm and from 39.46% to 19.29%, respectively. However, with the extension of grinding time, the reunion phenomenon was gradually increased, eventually formed larger particles aggregation. The creep and creep-recovery behavior results indicated that the creep deformation, creep compliance, and irreversible deformation were decreased with the increase of the cornstalk content untill reached 15%.When the content was up to 20%, the anticreep behavior trended to be weaken. Finally, fourcomponent Burgers model was used to fit creep strain and time data (R2>0.98).

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尹冬敏,吴敏,李栋.超微粉碎玉米秸秆微观结构与秸秆-淀粉共混膜蠕变特性[J].农业机械学报,2016,47(s1):297-304. Yin Dongmin, Wu Min, Li Dong. Microstructure of Ball Milling Cornstalk and Creep Behavior of Corn Starch-based Films[J]. Transactions of the Chinese Society for Agricultural Machinery,2016,47(s1):297-304.

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  • 收稿日期:2016-07-20
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  • 在线发布日期: 2016-10-15
  • 出版日期: 2016-10-15