废植物油脂与废聚乙烯塑料共裂解制备燃油研究
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国家自然科学基金项目(21266022、21466022)、国家国际科技合作专项(2015DFA60170)、国家高技术研究发展计划(863计划)项目(2012AA101800-03、2012AA021205-6、2014AA022002)和江西省科技重大专项(2012ABG04103)


Preparation of Fuel from Co-pyrolysis of Waste Vegetable Oil and Waste Polyethylene Plastics
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    摘要:

    研究在高压反应釜中,利用ZrO2/Al2O3/TiO2多晶泡沫陶瓷催化剂,催化废植物油脂与废聚乙烯塑料共裂解制备燃油。考察了温度、时间、催化剂添加比例、物料质量比等因素对废植物油脂与废聚乙烯塑料共裂解制备燃油的影响。得到适宜的制备条件为反应温度430℃、反应时间40min、催化剂质量分数15%、物料质量比1∶1,在此条件下,液体产物产率为65.9%。GC-MS分析表明,裂解液体中饱和烃类产物峰面积比例接近100%,其中97.85%为直链烷烃,并初步推断了废植物油脂与废聚乙烯塑料共裂解机理。产物的部分燃料油性能测定结果表明,裂解燃油热值明显高于生物柴油与0号柴油,密度和运动黏度符合0号柴油的标准,冷凝点和冷滤点均优于生物柴油,低温流动性好。

    Abstract:

    The production of high quality renewable hydrocarbon fuels through catalytic pyrolysis of waste vegetable oil and polyethylene with the ZrO2/Al2O3/TiO2 polycrystalline ceramic foam as catalyst in the high-pressure reaction kettle was carried out. The effects of reaction temperature, time, catalyst amount and material feeding ratio were investigated on the production of renewable hydrocarbon fuels through catalytic pyrolysis of waste vegetable oil and polyethylene. The optimal condition was achieved that the reaction temperature was 430℃, the reaction time was 40min, the dosage of the catalyst was 15%, the quality ratio of waste vegetable oil and waste polyethylene plastic was 1∶1, and liquid product yield was 65.9%. The GC-MS analysis indicated saturated hydrocarbon percentage of TIC peak areas in pyrolysis liquid product was close to 100%, 97.85% of which were straight-chain alkanes. The pyrolysis gas and liquid products were precisely analyzed to deduce co-pyrolysis with ZrO2/Al2O3/TiO2 polycrystalline ceramic foam catalyst mechanism. Pyrolysis oil properties were determined. Compared with biodiesel and 0# diesel, pyrolysis oil heat value was higher, and the density and viscosity were similar to 0# diesel. Freezing point and cold filter plugging point were better than those of biodiesel. The low temperature fluidity was good. It proved the feasibility to derive renewable hydrocarbon fuel from copyrolysis of waste vegetable oil and waste polyethylene plastics with ZrO2/Al2O3/TiO2 polycrystalline ceramic foam catalyst.

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王允圃,黄燕燕,戴磊磊,Ruan Roger,刘玉环,王小亮.废植物油脂与废聚乙烯塑料共裂解制备燃油研究[J].农业机械学报,2016,47(1):177-181. Wang Yunpu, Huang Yanyan, Dai Leilei, Ruan Roger, Liu Yuhuan, Wang Xiaoliang. Preparation of Fuel from Co-pyrolysis of Waste Vegetable Oil and Waste Polyethylene Plastics[J]. Transactions of the Chinese Society for Agricultural Machinery,2016,47(1):177-181.

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  • 收稿日期:2015-07-13
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  • 在线发布日期: 2016-01-10
  • 出版日期: 2016-01-10
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