砒砂岩改良风沙土对铵态氮吸附特性影响研究
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中国科学院西部行动计划资助项目(KZCX2-XB3-13-02)和教育部新世纪优秀人才支持计划资助项目(NCET-13-0487)


Effects of Soft Rock Modified Sandy Soil on NH+4 N Adsorption Characteristics
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    摘要:

    由于砒砂岩的广泛分布和煤炭资料的开发利用,晋陕蒙接壤区出现了一系列生态环境问题。为恢复区域生态,尝试利用区域内的砒砂岩来改良风沙土,以实现砒砂岩的资源化利用和受损生态系统的修复,本研究设计了风沙土中砒砂岩不同添加比例(0、10%、25%、50%、75%、90%、100%)的改良模式。研究了25℃下不同改良模式对NH+4 N吸附动力学和等温吸附特征的影响,评价了不同模型对改良土壤的适应性,以期为建立合理的氮肥施用指标和提高肥料利用率提供依据。结果表明:相同条件下,砒砂岩对NH+4 N的吸附量大于风沙土;随着砒砂岩添加比例的增加,改良土壤对NH+4 N的吸附量呈线性增加关系。砒砂岩的添加可以显著增加风沙土对NH+4 N的吸附,增加土壤供氮的持续性,提高肥料的有效性。准二级动力学模型可用于拟合改良土壤对NH+4 N的吸附动力学曲线。NH+4 N的等温吸附曲线以Freundlich模型拟合效果更优。各处理对NH+4N的吸附均为自发过程,且为有利吸附,吸附速率由膜扩散和颗粒内扩散共同控制。

    Abstract:

    Due to the widely existence of soft rock and the exploitation of coal resource, serious ecological and environmental problems occurred in the contiguous areas of Shanxi, Shaanxi and Inner Mongolia in China. In order to restore regionally ecological environment, this study was conducted to improve sandy soil using soft rock in the energy communities, and realize the transformation of soft rock into available resources. Previous research found that soft rock could improve hydraulic properties of sandy soil. But there are few researches about the nutrient availability of soft rock distributed into sandy soil. Soft rock was mixed in sandy soil with seven ratios: 0,10%,25%,50%,75%,90% and 100%. Adsorption kinetic were determined and fitted with Freundlich,Langmuir,Temkin and DubininRadushkevich models. Adsorption isotherms were measured and modeled with Pseudofirstorder, Pseudosecondorder, Biconstant and Intraparticle diffusion models. This study was conducted to understand the effects of different additive proportions of soft rock amended sandy soils on the adsorption of NH+4 N, and to select the optimal adsorption model of improved soil. The results can be used to guide reasonable fertilization of nitrogenous and improve the utilization efficiency of fertilize. The results showed that: with the extension of reaction times and the increase of equilibrium concentration, the NH+4 N adsorption capacity was increased in improved soil. Reaching to the adsorption equilibrium, sandy soil needs 4 hours and soft rock needs 16 hours. Adsorption capacity of NH+4 N was the largest in sandy soil and the least in soft rock, the maximum adsorption of NH+4 N in soft rock was 20 times of sand soil. With the increase of the soft rock proportion in improved soil, NH+4 N optimal adsorption was increased linearly. Soft rock could improve the NH+4 N adsorption capacity of sandy soil. The pseudosecondorder kinetic model and the Freundlich isotherm model could well describe NH+4 N absorption in improved soil. NH+4 N adsorption is a spontaneous process and a favorable adsorption.

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摄晓燕,魏孝荣,魏艳春,马天娥,许晶晶,张兴昌.砒砂岩改良风沙土对铵态氮吸附特性影响研究[J].农业机械学报,2015,46(11):165-173. She Xiaoyan, Wei Xiaorong, Wei Yanchun, Ma Tiane, Xu Jingjing, Zhang Xingchang. Effects of Soft Rock Modified Sandy Soil on NH+4 N Adsorption Characteristics[J]. Transactions of the Chinese Society for Agricultural Machinery,2015,46(11):165-173.

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  • 收稿日期:2015-06-07
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  • 在线发布日期: 2015-11-10
  • 出版日期: 2015-11-10